Work

Theory of Exciton Migration and Field-Induced Dissociation in Conjugated Polymers

Year: 1996
Type: article
Abstract: The interplay of migration, recombination, and dissociation of excitons in disordered media is studied theoretically in the low temperature regime. An exact expression for the photoluminescence spectrum is obtained. The theory is applied to describe the electric field-induced photoluminescence-quenching experiments by Kersting et al. [Phys. Rev. Lett. 73, 1440 (1994)] and Deussen et al. [Synth. Met. 73, 123 (1995)] on conjugated polymer systems. Good agreement with experiment is obtained using an on-chain dissociation mechanism, which implies a separation of the electron-hole pair along the polymer chain.
Language: English
Open Access status: green
OpenAlex ID: W1967110643
FWCI: 6.059
Cites: 19
Cited by: 56
Related to: 10