Work

Determination of hyperpolarizability tensor components by depolarized hyper Rayleigh scattering

Year: 1993

Type: article

Abstract: Depolarized hyper Rayleigh scattering of para-nitroaniline (${\mathit{C}}_{2\mathit{v}}$ symmetry) and nitrocalix[4]arene (${\mathit{C}}_{4\mathit{v}}$ symmetry) in solution has been measured. Using linearly and circularly polarized fundamental radiation information about the ratios between the several hyperpolarizability tensor components, including their sign, was obtained. Results are consistent with the theory developed for both symmetry groups. Comparison between experimental depolarization ratios and ratios obtained from ab initio calculated hyperpolarizability tensor components shows good agreement.

Source: Physical Review Letters

DOI: 10.1103/physrevlett.71.999

Authors: G. J. T. Heesink, A. G. T. Ruiter, N. F. van Hulst, B. Bölger

Institution: University of Twente

Language: English

Topic: Nonlinear Optical Materials Research

Subfield: Electronic, Optical and Magnetic Materials

Field: Materials Science

Domain: Physical Sciences

Open Access status: green

OpenAlex ID: W1968412997

FWCI: 6.819

Cites: 18

Cited by: 145

Related to: 10