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A General and Simple Removal of the Allyloxycarbonyl Protecting Group by Palladium-Catalyzed Reactions Using Nitrogen and Sulfur Nucleophiles

Year: 1993

Type: article

Abstract: All articles of this category Smooth removal of the Allyloxycarbonyl (Alloc) moiety from allylic esters, carbamates and carbonates is carried out by Pd (O) catalyzed allyl transfer to diethylamine and thio derivatives as the accepting nucleophiles. The method has been successfully used for selective deprotection of secondary amines and base sensitive substrates.

Source: Synlett

DOI: 10.1055/s-1993-22570

Authors: Jean Pierre Genêt, Errol Blart, Monique Savignac, Stéphane Lemeune, Sandrine Lemaire-Audoire, Jean Marie Bernard

Institutions: Centre National de la Recherche Scientifique, Chimie ParisTech - PSL, Laboratoire de Synthèse Organique

Language: English

Topic: Catalytic Cross-Coupling Reactions

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: green

OpenAlex ID: W1969989376

FWCI: 3.64

Cites:

Cited by: 49

Related to: 10