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Синтез метиловых эфиров 3,4-дигидрокси-6-оксо-2,4-алкадиеновых кислот

Year: 2014
Type: article
Abstract: Methyl 3,4-dihydroxy-6-oxo-2,4-alkadienoates are produced by the condensation reaction of methyl acetate, dimethyl oxalate and alkyl methyl ketones. The structure peculiarities of the synthesized compounds are discussed on the basis of IR and NMR1H spectroscopy data. It has been discovered that these compounds in the solid state and in nonpolar solvents exist as dienol bis-OH-chelate tautomers.
Language: Russian
Field: Chemistry
Open Access status: hybrid
OpenAlex ID: W19758002
FWCI:
Cites: 4
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Related to: 10