Work

Cis--Trans Influences in Pt Complexes. Crystal Structures of cis-[PtCl2(1,4-thioxane)2] and trans-[PtCl2(1,4-thioxane)2].

Year: 1993

Type: article

Abstract: The cis compound crystallizes in the space group P2 1 /n with a=10.614, b=11.283, c=11.015A, β=93.33°, Z=4. The refinement converged to R=0.057. The trans compound crystallizes in Pbca with a=7.959, b=8.972, c=18.590A, Z=4. The refinement converged to R=0.031. The coordination geometry is sqaure-planar in both compounds. In the cis compound the Pt-Cl distances are in the range 2.321-2.327A and the Pt-S distances are both 2.273A. In the trans compound the Pt-Cl and Pt-S distances are 2.300 and 2.298A

Source: Acta chemica Scandinavica/Acta chemica Scandinavica. B, Organic chemistry and biochemistry/Acta chemica Scandinavica. A, Physical and inorganic chemistry/Acta chemica Scandinavica. Series B. Organic chemistry and biochemistry/Acta chemica Scandinavica. Series A, Physical and inorganic chemistry

DOI: 10.3891/acta.chem.scand.47-0554

Authors: Zivadin Bugarcic, Karin Lövqvist, Åke Oskarsson, Gary M. Hewitt, James P. Kutney, Kai Li, Radka K. MIlanova, Hiroyuki Nakata, Ahmad Nasiri, Yoshito Okada

Language: English

Topic: Crystal structures of chemical compounds

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

OpenAlex ID: W1985643236

FWCI: 2.118

Cites:

Cited by: 21

Related to: 10