Electric-Field-Induced Polarization Enhancement of Vinylidene Fluoride/Trifluoroethylene Copolymer Ultrathin Films
Year: 2011
Type: article
Abstract: We investigated the polarization enhancement in 60-nm-thick vinylidene fluoride/trifluoroethylene (VDF/TrFE) films without thermal annealing by applying repeated bipolar electric pulses. The remnant polarization was 8.4 mC/m 2 in as-spin-coated films and increased to up to 45 mC/m 2 when 10 5 pulses were applied. Although the remnant polarization was half and the coercive field twice those of annealed films, the electrically treated film had a markedly smoother surface than the annealed film. Finally, a 15-nm-thick ferroelectric VDF/TrFE film with low conductivity was fabricated by electric treatment; annealed films with the same thickness experienced a severe short-circuit problem originating from the surface roughness.
Source: Applied Physics Express
Language: English
Field: Materials Science
Domain: Physical Sciences
Open Access status: bronze
OpenAlex ID: W1995774674
