Work

Synthese und Kristallstrukturen von Dimethylgalliumdiphenylphosphinat und Diethylindiumdiphenylphosphinat / Synthesis and Crystal Structures of Dimethylgalliumdiphenylphosphinate and Diethylindiumdiphenylphosphinate

Year: 1990

Type: article

Abstract: The synthesis of diethylindiumdiphenylphosphinate and the crystal structures of dimethylgalliumdiphenylphosphinate and diethylindiumdiphenylphosphinate are reported. The two structures confirm the proposed dimeric nature of the title compounds with bridging diphenylphosphinate groups. [Ph2P(O)2Ga(CH3)]2 crystallizes triclinically, PĪ, with a = 9.483(6), b = 10.216(4), c = 8.780(9)Å, α = 101.66(5)°, β = 113.74(5)°, γ = 69.93(5)° and Ζ = 1 (dimer). [Ph2P(O)2In(C2H5)2]2 crystallizes monoclinically, C2/c, with a = 19.971(5), b = 8.590(2), c = 19.457(5)Å, β = 102.91(2)° and Ζ = 4 (dimers). Both structures contain tetrahedrally coordinated phosphorous and metal atoms.

Source: Zeitschrift für Naturforschung B

DOI: 10.1515/znb-1990-0206

Authors: F. Ekkehardt Hahn, Bernd Schneider, Friedrich-Wilhelm Reier

Institutions: Technische Universität Berlin, Freie Universität Berlin, Fraunhofer Institute for Telecommunications, Heinrich Hertz Institute

Language: English

Topic: Synthesis and characterization of novel inorganic/organometallic compounds

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Estimated APC paid: $2,712

OpenAlex ID: W1996263222

FWCI: 1.655

Cites:

Cited by: 28

Related to: 10