Crystal structure of trans-dichloro-bis(N-p-cycanobenzylidene)-p-nhexyloxyaniline-palladium(II),C40H44Cl2N4O2PCI
Year: 2001
Type: article
Abstract: C4oH44Cl2N 4 C>2Pd, monoclinic, P12i/cl (No. 14), a = 17.358(1) k,b= 13.485(1) A,c = 8.471(1) A, β = 99.150(6)°,V= 1957.5A 3 , Z= 2, R^F) = 0.033, »vÄaiKF 2 ; = 0.093, T= 293 K. Source of materialIn order to obtain the title compound, 73.5 mg (0.2 mmol) of N-(/?-cyanobenzylidene)-p-n-hexyloxyaniline (from p-formylbenzonitrile and p-n-hexyloxyaniline in ethanol, 3 h) and 33.7 mg (0.11 mmol) of Na2PdCU were suspended in 5 ml of methanol and gave a light orange suspension.After stirring the mixture for 6 h the yellow precipate was centrifuged off, washed with diethylether and dried in vacuum.Crystals were obtained from a solution in dichloromethane (yield 64 mg, 78 %; mp 501 K).
Authors: K. Polbom, Ch.-U. Missling, W. Beck
Institution: Ludwig-Maximilians-Universität München
Language: German
Subfield: Inorganic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $848
OpenAlex ID: W1996580046