Work

Crystal surface mediated structure transformation of a kinetic framework composed of multi-interactive ligand TPHAP and Co(ii)

Year: 2012

Type: article

Abstract: A tripyridyl multi-interactive ligand TPHAP is prepared by a one-pot reaction on a gram scale. Network formation of Co(ii) with TPHAP(-) gave kinetic and thermally more stable products. The kinetic network showed an unprecedented dynamic network transformation on the crystal surface by a ligand exchange reaction.

Source: Chemical Communications

DOI: 10.1039/c2cc35078e

Authors: Yumi Yakiyama, Akira Ueda, Yasushi Morita, Masaki Kawano

Institutions: Pohang University of Science and Technology, The University of Osaka

Language: English

Topic: Metal-Organic Frameworks: Synthesis and Applications

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: green

Funder: Japan Society for the Promotion of Science

Awards: Development of discotic liquid crystal based on spin delocalized huge π conjugated organic radical, G3835595035, Precise synthesis and properties of open-shell graphenefragments with heteroatomic modification