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The activation of Woollins' reagent. Isolation of pyridine stabilised PhPSe 2

Year: 2014
Type: article
Abstract: Woollins' reagent (WR, (PhPSe2)2) plays an essential role in the selenation of organic compounds. Reaction of WR with pyridine gives the P(V) species PhPSe2 stabilised by pyridine coordination which is the first crystallographically characterised mononuclear RPSe2 system stabilised by an external molecule and has potential as a selenation reagent for reactions under mild conditions.
DOI: 10.1039/c4cc01073f
Authors: Laura Ascherl, Andreas Nordheider, Kasun S. Athukorala Arachchige, David B. Cordes, Konstantin Karaghiosoff, Michael Bühl, Alexandra M. Z. Slawin, J. Derek Woollins
Language: English
Field: Chemistry
Open Access status: hybrid
OpenAlex ID: W2005244286
FWCI: 0.95
Cites: 29
Cited by: 22
Related to: 10