Bis[μ-2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ4N2,N3:N4,N5]bis[(nitrato-κO)silver(I)] tetrahydrate
Year: 2013
Type: article
Abstract: The self-assembly of an angular 2,5-bis-(pyridin-2-yl)-1,3,4-thia-diazole ligand (L) with silver nitrate (AgNO3) produced a new dinuclear silver(I) coordination complex, [Ag2(C12H8N4S)2(NO3)2]·4H2O, which crystallizes with two Ag atoms bridged by two L ligands. The Ag atom is surrounded by four N atoms of L and by one O from the nitrate anion defining a distorted square pyramid. The atoms comprising the dication are nearly coplanar, with an r.m.s. deviation of 0.1997 Å. Mol-ecules are linked by C-H⋯O and O-H⋯O hydrogen bonds through nitrate anions and water mol-ecules, forming a two-dimensional porous network. The overall structure involves stacking of Ag complex layers along the b axis. The cohesion in the three-dimensional architecture is ensured by O⋯Ag inter-actions.
Institutions: Chouaib Doukkali University, Mohammed V University
Language: French
Subfield: Inorganic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $500
OpenAlex ID: W2005265350