Work

One‐Pot Synthesis of Poly(linoleic acid)‐ g ‐Poly(styrene)‐ g ‐Poly(ε‐caprolactone) Graft Copolymers

Year: 2014

Type: article

Abstract: One‐pot synthesis of graft copolymers by ring‐opening polymerization and free radical polymerization using polymeric linoleic acid peroxide (PLina) is reported. Graft copolymers having structures of poly(linoleic acid)‐ g ‐polystyrene‐ g ‐poly(ε‐caprolactone) were synthesized from PLina, possessing peroxide groups on the main chain by the combination of free radical polymerization of styrene and ring‐opening polymerization of ε‐caprolactone in one‐step. Principal parameters, such as monomer concentration, initiator concentration, and polymerization time, which effect the one‐pot polymerization reactions were evaluated. The obtained graft copolymers were characterized by 1 H‐NMR and DOSY‐NMR spectroscopy, gel permeation chromatography, thermal gravimetric analysis and differential scanning calorimetry techniques.

Source: Journal of the American Oil Chemists Society

DOI: 10.1007/s11746-014-2418-1

Authors: Abdulkadir Allı, Sema Allı, C. Remzi Becer, Baki Hazer

Institutions: Düzce Üniversitesi, Zonguldak Bülent Ecevit University, Queen Mary University of London

Language: English

Topic: biodegradable polymer synthesis and properties

Subfield: Biomaterials

Field: Materials Science

Domain: Physical Sciences

Open Access status: green

OpenAlex ID: W2005357732

FWCI: 0.773

Cites: 48

Cited by: 30

Related to: 10