Year: 2014
Type: article
Abstract: This work illustrates the use of basic statistical mechanics for rationalizing the loading of linear multitridentate polymers with trivalent lanthanides, Ln(III), and identifies the specific ionic sizes of europium and yttrium as promising candidates for the further design of organized heterometallic f–f′ materials. Using [Ln(hfac)3] (hfac = hexafluoroacetylacetonate) as lanthanide carriers, the thermodynamically controlled formation of Wolf type-II lanthanidopolymers [{Ln(hfac)3}m(L4)] is modeled with the help of two simple microscopic descriptors: (i) the intrinsic affinity of Ln(III) for the tridentate binding sites fN3(Ln) and (ii) the intermetallic interactions ΔE1–2(Ln,Ln) operating between two occupied adjacent sites. Selective complexation (fN3La << fN3Eu > fN3(Y)) modulated by anticooperative interactions (ΔE1–2(La,La) ≃ ΔE1–2(Eu,Eu) > ΔE1–2(Y,Y) ≈ 0) favors the fixation of Eu(III) in semiorganized lanthanidopolymers [{Eu(hfac)3}m(L4)] displaying exploitable light-downshifting.
Source: Inorganic Chemistry
DOI: 10.1021/ic4030525
Institution: University of Geneva
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $4,500
OpenAlex ID: W2007425072