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ESE relaxation measurements in photosystem II The influence of the reaction center non‐heme iron on the spin‐lattice relaxation of Tyr D.

Year: 1991
Type: article
Abstract: The spin-lattice relaxation of the tyrosine radical D. in Photosystem II particles was studied at 4.2 K in samples in which flash-induced oscillations of the oxidation state of the Mn-cluster of the oxygen evolving system were abolished by addition of ANT2P, leaving Fe2+/Fe3+ oscillations intact. Samples subjected to 0, 1 or 2 light-flashes all showed the same relaxation kinetics. No period-2 oscillation in the spin-lattice relaxation corresponding to the Fe2+/Fe(3+)-oscillation was observed. Thus the T1-oscillations of D. as a function of flash number in untreated samples are solely caused by the charge-oscillations of the Mn-cluster (1989, Biochim, Biophys. Acta 973, 428-442).
Source: FEBS Letters
Institution: Leiden University
Language: English
Open Access status: bronze
OpenAlex ID: W2010153706
FWCI: 0.223
Cites: 16
Cited by: 6
Related to: 10