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Structure and Bonding of Low-Valent (Fischer-Type) and High-Valent (Schrock-Type) Transition Metal Carbene Complexes

Year: 1998

Type: article

Abstract: The nature and reactivity of the metal–carbene bond of 12 Fischer- (1) and Schrock- (2) type carbene complexes of tungsten, both neutral and negatively charged, is investigated. The geometries and tungsten–carbene bond dissociation energies were calculated by use of ab initio methods at the HF, MP2, and CCSD(T) level of theory.

Source: Chemistry - A European Journal

DOI: 10.1002/(sici)1521-3765(19980807)4:8<1428::aid-chem1428>3.0.co;2-7

Authors: Sergei F. Vyboishchikov, Gernot Frenking

Institution: Philipps University of Marburg

Language: English

Topic: Organometallic Complex Synthesis and Catalysis

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: bronze

Funders: Philipps-Universität Marburg, Deutscher Akademischer Austauschdienst, Deutsche Forschungsgemeinschaft

OpenAlex ID: W2011491406

FWCI: 7.794

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Cited by: 157

Related to: 10