Work

Study of Sulfur-Sulfur Nonbonded Interactions in Substituted Diphosphine Disulfides by Gas-Phase UV Photoelectron Spectroscopy

Year: 1981

Type: article

Abstract: Ultraviolet photoelectron spectra (UPS) of tetrasubstituted diphosphine disulfides RR'P(S)- P(S)RR' exhibit peculiar 1:2:1 splitting patterns in the region 7.5-9.5 eV for which a throughbond coupling mechanism between the sulfur lone pairs lying in the PPS planes is proposed. Further bond orbitals are related to bands at higher I. E. in the UP spectra

Source: Zeitschrift für Naturforschung A

DOI: 10.1515/zna-1981-0111

Authors: Lucilla Alagna, Carla Cauletti, Marco Andreocci, Claudio Furlani, Gerhard Hagele

Institutions: National Research Council, Sapienza University of Rome, Heinrich Heine University Düsseldorf

Language: English

Topic: Advanced Chemical Physics Studies

Subfield: Atomic and Molecular Physics, and Optics

Field: Physics and Astronomy

Domain: Physical Sciences

Open Access status: hybrid

Estimated APC paid: $2,712

OpenAlex ID: W2012103859

FWCI:

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