Work

Vibrational and structural properties of unmodified and radiation-modified chalcogenide glasses for advanced optical applications

Year: 2008

Type: conference-paper

Abstract: Vibrational and structural properties of GexSb40 xS60 (x = 25, 27, 35) chalcogeide glasses are studied in unmodified and γ-radiation-modified states by using infrared spectroscopy, high-energy synchrotron x-ray diffraction and extended x-ray absorption fine structure spectroscopy. An agreement between radiation-induced structural changes and vibrational properties measured is established. It is suggested that the atomic pairs with wrong coordination created in the framework of coordination topological defect formation concept play a key role in the formation of radiation-modified state of the investigated glasses. Advantages and disadvantages of post-technological radiation-modification of chalcogenide glasses are considered within configuration coordinate model for description of unmodified and radiationmodified states.

Source: Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

DOI: 10.1117/12.815947

Authors: Taras Kavetskyy, Oleh Shpotyuk, Valentyna Balitska, Galyna Dovbeshko, Ivan Blonskyy, Ivan Kaban, Walter Hoyer, Mihail Iovu, Andrei Andriesh

Institutions: Jan Długosz University, Drohobych Ivan Franko State Pedagogical University, Institute of Physics, Chemnitz University of Technology

Language: English

Topic: Phase-change materials and chalcogenides

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: green

OpenAlex ID: W2016451839

FWCI: 3.872

Cites:

Cited by: 11

Related to: 10