Work

Steering the potential barriers: Entropic to energetic

Year: 2010
Type: article
Abstract: We propose a mechanism to alter the nature of the potential barriers when a biased brownian particle undergoes a constrained motion in narrow periodic channel. By changing the angle of the external bias, the nature of the potential barriers changes from purely entropic to energetic, which in turn affects the diffusion process in the system. At an optimum angle of the bias, the nonlinear mobility exhibits a striking bell-shaped behavior. Moreover, the enhancement of the scaled effective diffusion coefficient can be efficiently controlled by the angle of the bias. This mechanism enables the proper design of channel structures for transport of molecules and small particles. The approximate analytical predictions have been verified by precise brownian dynamics simulations.
Language: English
Open Access status: green
OpenAlex ID: W2018967183
FWCI: 2.261
Cites: 42
Cited by: 26
Related to: 10