Work

Oxidization Process of Fe–Ni Mixed Prussian Blue Analogue Investigated by Valence-Differential Spectroscopy

Year: 2011

Type: article

Abstract: The oxidization process of the Fe–Ni mixed Prussian blue analogue (Fe0.2Ni0.8)[Fe(CN)6]0.67·zH2O was investigated by means of valence-differential spectroscopy. The spectroscopy revealed that the oxidization process selectively starts from the intermediate clusters. With a further increase in the oxidization level, all intermediate clusters are oxidized, and then Fe-rich clusters begin to be oxidized. On the basis of these results, we will discuss the redox process of the Ni–Fe cyano mixed crystal.

Source: Japanese Journal of Applied Physics

DOI: 10.1143/jjap.50.032401

Authors: Ayako Omura, Yutaro Kurihara, Manabu Ishizaki, Masato Kurihara, Yutaka Moritomo

Institutions: University of Tsukuba, Yamagata University

Language: English

Topic: Inorganic Chemistry and Materials

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: bronze

Funders: Ministry of Education, Culture, Sports, Science and Technology, Japan Society for the Promotion of Science

Awards: Investigation of ion conductivity via interfaces among coordination polymer nanocrystals using their surface unsaturated coordination sites, Ion intercalation and functionality at Prussian blue interface, G5857023665