Work

A Group 13/Group 17 Analogue of CO and N2: Coordinative Trapping of the GaI Molecule

Year: 2008

Type: article

Abstract: The first row diatomic molecules N2 and CO have played central roles in developing fundamental models of electronic structure, and their interactions with transition metals have been widely investigated. By contrast, the valence isoelectronic molecules EX (E = group 13 element, X = group 17 element) have yet to be isolated under ambient conditions, either as the "free" molecule or as a simple metal complex. Here, we find that iodide abstraction from Cp*Fe(dppe)(GaI2) yields the stable complex [Cp*Fe(dppe)(GaI)]+ which features a terminally bound GaI ligand, characterized by a near linear (but readily deformed) Fe-Ga-I geometry and by very short Fe-Ga and Ga-I distances. Chemical and computational evidence reveal a relatively weak metal-ligand bond similar in strength to that found for dinitrogen analogues.

Source: Journal of the American Chemical Society

DOI: 10.1021/ja800876k

Authors: Natalie D. Coombs, William Clegg, Amber L. Thompson, David J. Willock, Simon Aldridge

Institutions: University of Oxford, Newcastle University

Language: English

Topic: Synthesis and characterization of novel inorganic/organometallic compounds

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: green

Funder: Engineering and Physical Sciences Research Council

Award: National Crystallography Service 2006 Renewal