Crystal structure of pentacarbonyl [(ethoxycarbonyl)- (N-diphenylmethylenamino) methylene]chromium(0), Cr(CO)5[C(COOC2H5){NC(C6H5)2}]
Year: 2005
Type: article
Abstract: C22Hi5CrNC>7, monocLinie, P\2\ln\ (no. 14), a = 9.7086(9) A, b = 21.743(2)A, c = 10.801(1)A, β = 109.594(1)°,V= 2148.1 A 3 , Z = 4, R^F) = 0.038, wRrttfF 2 ) = 0.098, T= 183 K. Source of materialThe title complex was prepared by metathesis of the diphenylmethylene Schiff base of dehydroalanine ethyl ester with the Fischer carbene complex (OC)sCr=C(Ph)(OMe) [1], Orange-red plate-like crystals were obtained from a solution in n-hexane at 4 °C.
Authors: W. Ponikwar, H. Nöth, Η. Dialer, W. Beck
Institution: Ludwig-Maximilians-Universität München
Language: German
Subfield: Inorganic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $848
OpenAlex ID: W2092468041