Work

FeII Spin‐Crossover Phenomenon in the Pentadecanuclear {Fe9[Re(CN)8]6} Spherical Cluster

Year: 2015

Type: article

Abstract: The self-assembly of iron(II) ions with rare octacyanidorhenate(V) metalloligands in a methanolic solution results in the formation of a nanometric pentadecanuclear {Fe(II) 9 [Re(V) (CN)8 ]6 (MeOH)24 }⋅10 MeOH (1) molecule with a six-capped body-centered cubic topology. The cluster demonstrates a thermally-induced spin-crossover phase transition at T1/2 =195 K which occurs selectively for a single Fe(II) ion embedded in the center of a cluster core.

Source: Angewandte Chemie International Edition

DOI: 10.1002/anie.201500288

Authors: Szymon Chorazy, Robert Podgajny, Koji Nakabayashi, Jan Stanek, Michał Rams, Barbara Sieklucka, Shin‐ichi Ohkoshi

Institutions: Jagiellonian University, The University of Tokyo, Japan Science and Technology Agency

Language: English

Topic: Magnetism in coordination complexes

Subfield: Electronic, Optical and Magnetic Materials

Field: Materials Science

Domain: Physical Sciences

Open Access status: green

OpenAlex ID: W2124159444

FWCI: 2.804

Cites: 68

Cited by: 70

Related to: 10