Work

Synthesis of Enantiomerically Pure 1,2-Disubstituted 2-Selenoamines

Year: 2011
Type: article
Abstract: Optically pure phenylseleno-(S)-2-p-tolylsulfinylbenzylcarbanions react with (S)-N-2-p-tolylsulfinylimines derived from aliphatic and aromatic aldehydes in a highly stereoselective manner affording bis-sulfinylselenoamines, easily transformed into 1-phenyl, 2-aryl (or alkyl)-2-phenylseleno ethylamines by subsequent reactions, which were treatment reactions with t-BuLi and TFA. Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file.
Language: English
Field: Chemistry
Open Access status: green
OpenAlex ID: W2140285265
FWCI: 0.139
Cites: 27
Cited by: 2
Related to: 10