Work

Iron-catalyzed hydrosilylation of CO 2 : CO 2 conversion to formamides and methylamines

Year: 2014

Type: article

Abstract: Catalytic hydrosilylation of CO 2 is an efficient and selective approach to form chemicals. Herein, we describe the first iron catalysts able to promote the reductive functionalization of CO 2 using hydrosilanes as reductants. Iron( ii ) salts supported by phosphine donors enable the conversion of CO 2 to formamide and methylamine derivatives under mild reaction conditions.

Source: Catalysis Science & Technology

DOI: 10.1039/c4cy00130c

Authors: Xavier Frogneux, Olivier Jacquet, Thibault Cantat

Institutions: Centre National de la Recherche Scientifique, Commissariat à l'Énergie Atomique et aux Énergies Alternatives, CEA Paris-Saclay - Etablissement de Saclay, Institut Rayonnement-Matière de Saclay, Service Interdisciplinaire sur les Systèmes Moléculaires et les Matériaux

Language: English

Topic: Carbon dioxide utilization in catalysis

Subfield: Process Chemistry and Technology

Field: Chemical Engineering

Domain: Physical Sciences

SDG: Climate action

Open Access status: green

OpenAlex ID: W2155810941

FWCI: 10.75

Cites: 39

Cited by: 179

Related to: 10