Work

Functional representation for the grand partition function of a multicomponent system of charged particles: Correlation functions of the reference system

Year: 2006

Type: article

Abstract: Based on the method of collective variables (CV) with a reference system, the exact expression for the functional of the grand partition function of a m-component ionic model with charge and size asymmetry is found.Particular attention is paid to the nth particle correlation functions of the reference system which is presented as a m-component system of "colour" hard spheres of the same diameter.A two-component model is considered in more detail.In this case the recurrence formulas for the correlation functions are found.A general case of a m-component inhomogeneous system of the "colour" hard spheres is also analysed.

Source: Condensed Matter Physics

DOI: 10.5488/cmp.9.4.659

Authors: Patsahan, Mryglod

Institution: Yukhnovskii Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine

Language: English

Topic: Electrostatics and Colloid Interactions

Subfield: Physical and Theoretical Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: National Academy of Sciences of Ukraine, Centre National de la Recherche Scientifique

OpenAlex ID: W2184745772