Work

2-(4-Chlorobenzoyl)-1-(diaminomethylene)hydrazinium chloride monohydrate

Year: 2010

Type: article

Abstract: In the cation of the title compound, C(8)H(10)ClN(4)O(+)·Cl(-)·H(2)O, the guanidinium group is planar (maximum deviation = 0.0001 Å) and nearly perpendicular to carboxamide group, making a dihedral angle of 87.0 (3)°. The N atoms of the guanidine fragment have a planar trigonal configuration and the N atom of the carboxamide group adopts a pyramidal configuration. In the crystal structure, inter-molecular N-H⋯O, N-H⋯Cl and O-H⋯Cl hydrogen bonds link the cations, anions and water mol-ecules into layers parallel to the bc plane.

Source: Acta Crystallographica Section E Structure Reports Online

DOI: 10.1107/s1600536810014108

Authors: V. M. Chernyshev, A. V. Chernysheva, E. V. Tarasova, V. V. Ivanov, Z. A. Starikova

Institutions: Platov South-Russian State Polytechnic University, A. N. Nesmeyanov Institute of Organoelement Compounds

Language: English

Topic: Crystal structures of chemical compounds

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $500

OpenAlex ID: W2298335481

FWCI: 0.167

Cites: 11

Cited by: 2

Related to: 10