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1,2-hydrogen Migration in Aminoalkyl Radicals

Year: 2016

Type: article

Abstract: The amination reaction of α-olefins C4-C7 in the oxidation-reduction system NН2OH∙HCl-TiCl3 has been investigated; as a result the mono- and diamines of various structures have been prepared. It has been found that in attack of -radical to olefin it takes place a hydrogen migration from first carbon to second one. It has been shown that in composition of the reaction products besides purposeful individual amines there are detected telomers, the molecular masses of which are changed approximately within the ranges of, Мn = 460-800.

Source: European Chemical Bulletin

DOI: 10.17628/ecb.2016.5.495-500

Authors: Aslanova, Elnara Telman, Aslanov, Telman Agakerim, Bektashi, Nazim Rauf, Azizov, Akif Hamid, Nurullayeva, Dilbar Rushan

Institutions: Azerbaijan National Academy of Sciences, Polimer Materialları İnstitutu

Language: English

Topic: Radical Photochemical Reactions

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: bronze

OpenAlex ID: W2592837320

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