The Effect of Carbon Dioxide on the Cycle Life and Electrolyte Stability of Li-Ion Full Cells Containing Silicon Alloy
Year: 2017
Type: article
Abstract: Carbon dioxide is shown to be an effective additive to standard Li-ion electrolyte for extending the cycle life of full pouch cells containing an engineered silicon alloy. CO 2 was introduced to pouch cells by adding a few milligrams of dry ice to cells before sealing. The cells contained composite negative electrodes formulated with 15 to 17 wt% of an engineered silicon alloy and a LiCoO 2 positive electrode. Parasitic electrolyte reactions were measured in-situ by isothermal micro-calorimetry and high precision coulometry and compared to cells containing 1-fluoro ethylene carbonate (FEC). Extended cycling of cells containing CO 2 were compared to cells containing FEC. Cell gas generation and gas consumption were measured by applying the Archimedes principle. A new approach using small tubes in pouch cells to differentiate volume changes from gassing and solid expansion is introduced. Cells with CO 2 showed significantly lower parasitic thermal power, improved coulombic efficiency and better capacity retention compared to cells containing electrolytes with FEC. The gas generation/consumption experiments showed that Si alloy reacts with CO 2 during cycling until it is fully consumed. Combining FEC and CO 2 reduces the consumption rate of CO 2 . Microscopy of cross-sectioned cycled electrodes showed a thin SEI layer and minimal silicon alloy erosion. The combined work establishes CO 2 as a powerful precursor to an effective SEI layer on silicon alloys. Finally, CO 2 is shown to be an effective SEI former for graphite in EC-free electrolytes.
DOI: 10.1149/2.1121712jes
Authors: L. J. Krause, V. L. Chevrier, L. D. Jensen, T. Brandt
Institution: 3M (United States)
Language: English
Subfield: Electrical and Electronic Engineering
Field: Engineering
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $1,950
OpenAlex ID: W2749074331