A robust and unique iron( ii ) mosaic-like MOF
Year: 2018
Type: article
Abstract: A novel extended triazole-based ligand (PM-Tria) has been synthesized and an unprecedented MOF 3D has serendipitously been formed by assembling iron(ii), PM-Tria ligand and fluoride anions. This MOF contains a perfectly linear one-dimensional {Fe(ii)-F}n bridging chain that shows an antiferromagnetic behaviour. Furthermore, the structure is compared with a 14th century mosaic found in the Alhambra Palace in Granada showing a surprising symmetry resemblance.
Source: Chemical Communications
DOI: 10.1039/c8cc01561a
Institutions: Madrid Institute for Advanced Studies, IMDEA Nanoscience, Lawrence Berkeley National Laboratory, Advanced Light Source, Institut Català d'Investigació Química, Barcelona Institute of Science and Technology, Institució Catalana de Recerca i Estudis Avançats, Universidad Complutense de Madrid
Language: English
Subfield: Inorganic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: green
OpenAlex ID: W2799607136