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Simple and Green Adipic Acid Synthesis from Cyclohexanone and/or Cyclohexanol Oxidation with Efficient (NH4)xHyMzPMo12O40 (M: Fe, Co, Ni) Catalysts

Year: 2018

Type: article

Abstract: The oxidation of cyclohexanone and/or cyclohexanol to adipic acid (AA) was performed at 90 °C with a reaction time of 20 h, in the presence of H2O2 as oxidant and transition metal substituted ammonia polyoxometalates of formula, (NH4)xHyMzPMo12O40 (M: Fe, Co, or Ni, and x = 2.5 or 2.28) as catalysts. The catalytic results showed that the AA yield is sensitive to the transition metal nature and to the reaction conditions (sample weight and substrate amount). The (NH4)2.29H0.39Co0.16PMo12O40 was found to be the better catalytic system toward AA synthesis from cyclohexanone oxidation, with 40% of AA yield

Source: BULLETIN OF CHEMICAL REACTION ENGINEERING AND CATALYSIS

DOI: 10.9767/bcrec.13.2.1749.386-392

Authors: Sihem Mouanni, Tassadit Mazari, Sihem Benadji, Leila Dermeche, Catherine Marchal-Roch, Cherifa Rabia

Institutions: University of Sciences and Technology Houari Boumediene, Mouloud Mammeri University of Tizi-Ouzou, Centre National de la Recherche Scientifique, Université de Versailles Saint-Quentin-en-Yvelines, Institut Lavoisier de Versailles

Language: English

Topic: Polyoxometalates: Synthesis and Applications

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: gold

Estimated APC paid: $150

OpenAlex ID: W2805832200

FWCI: 0.35

Cites: 27

Cited by: 7

Related to: 10