Work

Desulfinative and denitrogenative palladium‐catalyzed cross‐coupling of arylsulfonyl hydrazides with aryl diazonium salts

Year: 2018

Type: article

Abstract: Palladium‐catalyzed cross‐coupling of arylsulfonyl hydrazides with aryl diazonium salts to provide biaryl products under relatively mild conditions is established. This reaction proceeded smoothly with tetrabutylammonium iodide and gave the corresponding products with CC bonds formed using PdCl2/bis (dicyclohexylphosphino) methane catalyst under air. This method also allowed easy access to significant functional biaryls for potential applications in medicinal and organic chemistry.

Source: Applied Organometallic Chemistry

DOI: 10.1002/aoc.4484

Author: Yonghui Shang

Institution: Xianyang Normal University

Language: English

Topic: Catalytic Cross-Coupling Reactions

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: bronze

Funders: National Natural Science Foundation of China, Natural Science Foundation of Shaanxi Province, Xianyang Normal University

Awards: G350000794, 手性药物分子与生物大分子相互作用的化学信息学解析研究, G881869955