Work

BINOLs modified at 3, 3′-positions: chemists’ preferred choice in asymmetric catalysis

Year: 2015

Type: article

Abstract: This article provides a general overview of the most relevant topics in the applications of BINOL modified at the 3 and 3′-positions in asymmetric catalysis.A brief introduction to the chiral BINOL backbone so modified is given.A selection of the most outstanding uses of the catalysts according to the functional groups at the 3,3′-positions of BINOL backbones such as 3,3′-disubstituents of BINOLs, phosphoric acid derivatives and phosphoramidites is then presented.This review aims to introduce the latest developments of this active field, including the literature since 2008.

Source: ARKIVOC

DOI: 10.3998/ark.5550190.p009.060

Authors: Guozhu Li, Fengjiao Liu, Mingshu Wu

Institution: Hainan Normal University

Language: English

Topic: Asymmetric Synthesis and Catalysis

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: National Natural Science Foundation of China, Hainan Normal University

Award: G9000187377