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Halogen Bonds (N---I) at Work: Supramolecular Catemeric Architectures of 2,7-Dipyridylfluorene with ortho -, meta -, or para -Diiodotetrafluorobenzene Isomers

Year: 2020
Type: article
Abstract: Supramolecular assemblies of 2,7-dipyridylfluorene with diiodotetrafluorobenzene isomers were obtained by mechanochemical synthesis, and their structures were determined by single crystal X-ray diffraction. The contribution of specific noncovalent interactions between different building blocks to the stability and solid-state packing behaviors of the supramolecular catemers was evaluated by theoretical methods, which confirm the geometries and interactional bonding observed in single crystal X-ray diffraction structures.
DOI: 10.1021/acs.cgd.0c00205
Authors: Ioana Georgeta Grosu, Lidia Pop, Maria Miclǎuş, Niculina Daniela Hǎdade, Anamaria Terec, Attila Bende, Crina Socaci, Mihail Barboiu, Ion Grosu
Institutions: Babeș-Bolyai University, National Institute for Research and Development of Isotopic and Molecular Technologies, École Nationale Supérieure de Chimie de Montpellier, Centre National de la Recherche Scientifique, Université de Montpellier, Institut Européen des Membranes
Language: English
Field: Chemistry
Open Access status: green
Award: G636304166
OpenAlex ID: W3013972920
FWCI: 1.829
Cites: 67
Cited by: 20
Related to: 10