Work

N - and O -arylation of pyridin-2-ones with diaryliodonium salts: base-dependent orthogonal selectivity under metal-free conditions

Year: 2020

Type: article

Abstract: -arylation reactions smoothly proceeded with the use of quinoline in chlorobenzene, leading to high yields and selectivities. In these methods, a variety of pyridin-2-ones in addition to pyridin-4-one and a set of diaryliodonium salts were accepted as suitable reaction partners.

Source: Chemical Science

DOI: 10.1039/d0sc02516j

Authors: Masami Kuriyama, Natsumi Hanazawa, Yusuke Abe, Kotone Katagiri, Shimpei Ono, Kosuke Yamamoto, Osamu Onomura

Institution: Nagasaki University

Language: English

Topic: Oxidative Organic Chemistry Reactions

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

Funders: Takeda Science Foundation, Ministry of Education, Culture, Sports, Science and Technology, Ritsumeikan University, Japan Society for the Promotion of Science

Awards: Development and application of the selective oxidation for alcohols by Pd catalysis, Synthesis of N,S-Heterocycles by 1,3-Dipolar Cycloaddition, G5924325237, Asymmetric Molecular Transformation of Glycerines Based on Activation of Hydroxyl Groups, G7654109522

OpenAlex ID: W3045348490

FWCI: 2.608

Cites: 56

Cited by: 45

Related to: 10