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A review of the evolution of the nanostructure of SiCN and SiOC polymer derived ceramics and the impact on mechanical properties

Year: 2020
Type: article
DOI: 10.1039/d0me00123f
Language: English
Open Access status: closed
Award: IN ORDER TO CONTINUE EXPLORING DEEP SPACE AND TO CREATE THE CAPABILITIES OF ALLOWING MANNED EXPLORATION TO MARS AND BEYOND NASA HAS STATED THAT IT IS VITAL TO DEVELOP NEW POWER GENERATION TECHNOLOGIES THAT CAN POWER OUR FUTURE SPACECRAFT MORE EFFICIENTLY WHILE SIMULTANEOUSLY MINIMIZING MASS AND MAINTAINING RELIABILITY. THERMOELECTRIC DEVICES PROVIDE A SIMPLE WAY TO CONVERT HEAT INTO ELECTRICITY WITHOUT ANY MOVING PARTS PROMOTING LONGTERM MAINTENANCE FREE OPERATION. HOWEVER CURRENT STATE OF THE ART TECHNOLOGIES ARE LIMITED IN THAT THEY ACHIEVE AN OPERATIONAL EFFICIENCY OF AROUND 6 TO 7 PERCENT ARE MADE OF EXPENSIVE AND HAZARDOUS MATERIALS AND REQUIRE A VERY LARGE THERMAL GRADIENT IN ORDER TO PRODUCE ANY USEABLE POWER. OVER THE LAST DECADE THEORETICAL AND EXPERIMENTAL WORK HAS PROVED THAT NANOSTRUCTURING OF THE THERMOELECTRIC MATERIALS PROVIDES A VERY PROMISING MEANS FOR EFFECTIVELY INCREASING THE OPERATIONAL EFFICIENCY THROUGH MEANS OF QUANTUM CONFINEMENT. THROUGH QUANTUM CONFINEMENT IT HAS BEEN SHOWN THAT THE ELECTRICAL AND THERMAL TRANSPORT OF A MATERIAL CAN BE DECOUPLED AND PROVIDE A MEANS OF INCREASING THE EFFICIENCY THROUGH INCREASING THE FIGURE OF MERIT GIVEN BY ZT=F2OT/K WHERE F IS SEEBECK COEFFICIENT O IS ELECTRICAL CONDUCTIVITY AND K IS THERMAL CONDUCTIVITY. WHILE VARIOUS TYPES OF MATERIALS HAVE BEEN USED TO FABRICATE THERMOELECTRICS WITH A DECENT ZT THERMALLY AND CHEMICALLY STABLE THERMOELECTRIC MATERIALS MADE FROM EARTH ABUNDANT MATERIALS ARE STILL REQUIRED FOR DEEP SPACE EXPLORATION. THE RESEARCH PROPOSED WITHIN AIMS TO FURTHER EXPLORE THIS AREA OF NANOSTRUCTURED THERMOELECTRICS BY CREATING A NEW THERMOELECTRIC MATERIAL BASED OFF OF POLYMER DERIVED CERAMICS. POLYMER DERIVED CERAMICS (PDCS) ARE A CLASS OF SILICON BASED AMORPHOUS CERAMIC MATERIALS THAT ARE CREATED THROUGH THE THERMAL DECOMPOSITION OF POLYMERIC PRECURSORS. PDCS OFFER A VERY HIGH THERMAL STABILITY (~1300-1500OC) HAVE A HIGH MECHANICAL STRENGTH AS WELL AS OXIDATION CORROSION AND IRRADIATION STABILITY. LIKE THEIR POLYMERIC PRECURSORS THEY ALSO POSSESS AN INHERENTLY LOW THERMAL CONDUCTIVITY. HOWEVER SIMPLE PDCS FACE THE CHALLENGES OF LOW ELECTRICAL CONDUCTIVITY AND CHARGE CARRIER DENSITIES. IT IS HYPOTHESIZED THAT 1) INTRODUCING ANISOTROPIC GRAPHENE FILLERS INTO THE AMORPHOUS SICN PDC MATRIX IMPROVES THE CHARGE TRANSPORT EFFICIENCY BUT DOES NOT CONTRIBUTE SIGNIFICANTLY TO PHONON TRANSPORT DUE TO MULTIPLE LENGTH SCALE SCATTERING 2) THE BAND STRUCTURE OF SICN CAN BE TUNED FOR EFFICIENT CHARGE TRANSFER AT SICN/CARBON INTERFACES AND 3) INCORPORATING NICKEL NANOPARTICLES INTO SICN COMPOSITE INCREASES THE SCATTERING OF LOW ENERGY ELECTRONS AND REDUCES THE ELECTRON PHONON COUPLING LEADING TO AN INCREASE OF THE FIGURE OF MERIT. TO VALIDATE THESE HYPOTHESES I WILL FIRST SYNTHESIZE AND CHARACTERIZE PURE POLYMER-DERIVED SICN CERAMICS AND THE GRAPHENE/NANOPARTICLE EMBEDDED SICN NANOCOMPOSITES FOLLOWED BY A SYNERGISTIC STRUCTURAL CHARACTERIZATION TO UNDERSTAND HOW THE CERAMIC COMPOSITION AND PYROLYSIS TEMPERATURE AFFECT THE CERAMIC STRUCTURES. THE SUBSEQUENT EVALUATION AND COMPARISON OF THE THERMOELECTRIC PROPERTIES OF PURE SICN AND SICN NANOCOMPOSITES WILL REVEAL THE EFFECT OF GRAPHENE METAL NANOPARTICLES AND NANOSCALE STRUCTURES ON THE CHARGE CARRIER DENSITY ELECTRICAL CONDUCTIVITY THERMAL CONDUCTIVITY SEEBECK COEFFICIENT AND THE FIGURE OF MERIT ZT. SUCH UNDERSTANDINGS WILL PROVIDE SCIENTIFIC GUIDELINES FOR THE DESIGN SYNTHESIS AND APPLICATIONS OF PDC COMPOSITES WITH SIGNIFICANTLY IMPROVED THERMOELECTRIC PERFORMANCE.
OpenAlex ID: W3097009336
FWCI: 3.461
Cites: 229
Cited by: 71
Related to: 10