Work

Removal of triclosan from aqueous solution using thermally treated rice husks

Year: 2020

Type: article

Abstract: ABSTRACT This study investigated triclosan removal using rice husks thermally treated at 100°C, 300°C, and 500°C. Rice husks were characterized by analyzing their surface morphologies, pore size, pore diameter, specific surface area, elemental composition, and chemical functional groups. The rice husks thermally treated at 300°C (RH-300) displayed higher triclosan removal efficiency than those treated at other temperatures. Adsorption of triclosan onto RH-300 was achieved within 4 h, and the kinetic adsorption data were well described by a pseudo-first-order model. The Langmuir model described the equilibrium adsorption of triclosan to RH-300 more suitably than the Freundlich model did, indicating that triclosan was adsorbed on RH-300 as a monolayer. Positive enthalpy changes and negative free energy change obtained from thermodynamic experiments indicated that triclosan adsorption by RH-300 was endothermic and spontaneous under these experimental conditions. A decrease in triclosan adsorption with an increase in solution pH was more obvious in the RH-300 dosage of 3.33 than 6.67 g/L. As fulvic acid increased from 0–10 mg/L, triclosan adsorption onto RH-300 decreased by 25.3%; changes in triclosan adsorption were not distinct above 10 mg/L. In conclusion, RH-300 is a low-cost and effective material for the removal of triclosan from aqueous solutions.

Source: Desalination and Water Treatment

DOI: 10.5004/dwt.2020.26161

Authors: Mutiara Triwiswara, Jin-Kyu Kang, Joon-Kwan Moon, Chang-Gu Lee, Seong-Jik Park

Institutions: Hankyong National University, Seoul National University, Ajou University

Language: English

Topic: Adsorption and biosorption for pollutant removal

Subfield: Water Science and Technology

Field: Environmental Science

Domain: Physical Sciences

SDGs: Responsible consumption and production, Clean water and sanitation

Open Access status: hybrid

Estimated APC paid: $1,000