Work

Electron belt-to-σ-hole switch of noncovalently bound iodine( i ) atoms in dithiocarbamate metal complexes

Year: 2021

Type: article

Abstract: The nature of metals in the isostructural series of dithiocarbamate complexes affects the electron belt-to-σ-hole switch of noncovalently bound iodine( i ) leading to either semicoordination, or halogen bonding.

Source: Inorganic Chemistry Frontiers

DOI: 10.1039/d1qi00314c

Authors: Lev E. Zelenkov, Anastasiya A. Eliseeva, Sergey V. Baykov, Vitalii V. Suslonov, Bartomeu Galmés, Antonio Frontera, Vadim Yu. Kukushkin, Daniil M. Ivanov, Nadezhda A. Bokach

Institutions: St Petersburg University, ITMO University, Universitat de les Illes Balears, South Ural State University

Language: English

Topic: Crystallography and molecular interactions

Subfield: Physical and Theoretical Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: bronze

Funders: Russian Foundation for Basic Research, Saint Petersburg State University, Division of Materials Research

Award: G3640248678

OpenAlex ID: W3136934848

FWCI: 4.187

Cites: 109

Cited by: 67

Related to: 10