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Synthesis and Mechanical Properties of Epoxy Composites Reinforced with Phosphazene Microspheres

Year: 2014
Type: article
Abstract: Using precipitation polymerization to synthesize polycyclotriphosphazene-sulfone microspheres with hexachlorocyclotriphosphazene and 4,4-sulfonyldiphenol and filled epoxy matrix to prepare composites to study the thermal and mechanical modified mechanisms. Polycyclotriphosphazene-sulfone microspheres has an average particle diameter of 500 nm, the initial decomposition temperature is 457.5 °C and the solid residual rate at 600 °C is 63.1 %. The tensile strength (55.95 MPa), impact strength (25.46 KJ/m2), flexural strength (140.65 MPa), elongation at break (38.6 %) of the EPM-3 composite material are 1.44, 2.74, 1.61, 1.89 times of EPM-0, respectively. Polycyclotriphosphazene-sulfone microspheres uniformly dispersed in the epoxy matrix and effectively improve the Tg and thermostability of the composites.
Language: English
Open Access status: diamond
OpenAlex ID: W4245976019
FWCI:
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Cited by: 1
Related to: 10