Influence of the Surface Chemistry of Metal–Organic Polyhedra in Their Assembly into Ultrathin Films for Gas Separation
Year: 2022
Type: article
Abstract: High Resolution Image Download MS PowerPoint Slide The formation of ultrathin films of Rh-based porous metal–organic polyhedra (Rh-MOPs) by the Langmuir–Blodgett method has been explored. Homogeneous and dense monolayer films were formed at the air–water interface either using two different coordinatively alkyl-functionalized Rh-MOPs (HRhMOP(diz) 12 and HRhMOP(oiz) 12 ) or by in situ incorporation of aliphatic chains to the axial sites of dirhodium paddlewheels of another Rh-MOP (OHRhMOP) at the air–liquid interface. All these Rh-MOP monolayers were successively deposited onto different substrates in order to obtain multilayer films with controllable thicknesses. Aliphatic chains were partially removed from HRhMOP(diz) 12 films post-synthetically by a simple acid treatment, resulting in a relevant modification of the film hydrophobicity. Moreover, the CO 2 /N 2 separation performance of Rh-MOP-supported membranes was also evaluated, proving that they can be used as selective layers for efficient CO 2 separation.
Institutions: Universidad de Zaragoza, Instituto de Nanociencia y Materiales de Aragón, Institut Català de Nanociència i Nanotecnologia, Barcelona Institute of Science and Technology, Synchrotron SOLEIL, Centre National de la Recherche Scientifique, Sorbonne Université, Institut des NanoSciences de Paris
Language: English
Subfield: Inorganic Chemistry
Field: Chemistry
Domain: Physical Sciences
Open Access status: hybrid
Estimated APC paid: $5,000
Funders: National Science Foundation, “la Caixa” Foundation, Centres de Recerca de Catalunya, Institut Català de Nanociència i Nanotecnologia, European Commission, Generalitat de Catalunya, Ministerio de Ciencia e Innovación, Gobierno de Aragón, Fundación Bancaria Caixa d'Estalvis i Pensions de Barcelona, Agència de Gestió d'Ajuts Universitaris i de Recerca, Departament d'Universitats, Recerca i Societat de la Informació, Secretaría de Estado de Investigación, Desarrollo e Innovación, European Regional Development Fund, Agencia Estatal de Investigación, Division of Materials Research
Awards: G1622782223, G1640339847, G1689194922, G1819776118, G2038104832, G2064873908, G2084050320, G2110243209, G2355262757, G2462415295, G2673512141, G279363373, G2825053243, G288263039, G2913093573, G3005324705, G3020948319, G3261693824, G3288897321, G3318976199, G3522231704, G3546882995, G3845300180, G4091044152, G410571670, G4310665315, G4351429150, G451917667, G4600716293, G4993383890, G5195188938, G5539308778, G5554424168, G5652914482, G5852091828, G5955501538, G5967599077, G6256622092, World class Science and Innovation with Neutrons in Europe 2020 – SINE2020, G6271517897, G6298273575, G6656126374, G69051668, G691065101, IMR-MIP DANSE - Distributed Data Analysis for Neutron Scattering Experiments - CNST, G7425137858, G7955708144, G8637226926, G8873697521, G929308097
OpenAlex ID: W4281740705