Work

Seasonal and Spatial Variations of PM10 and PM2.5 Oxidative Potential in Five Urban and Rural Sites across Lombardia Region, Italy

Year: 2022

Type: article

Abstract: samples collected at five urban and background sites near Milan (Italy), one of the largest and most polluted urban areas in Europe, afflicted with high particle levels. OP responses from two acellular assays, based on ascorbic acid (AA) and dithiothreitol (DTT), were combined with atmospheric detailed composition to examine any possible feature in OP with PM size fraction, spatial and seasonal variations. A general association of volume-normalized OP with PM mass was found; this association may be related to the clear seasonality observed, whereby there was higher OP activity in wintertime at all investigated sites. Univariate correlations were used to link OP with the concentrations of the major chemical markers of vehicular and biomass burning emissions. Of the two assays, AA was particularly sensitive towards transition metals in coarse particles released from vehicular traffic. The results obtained confirm that the responses from the two assays and their relationship with atmospheric pollutants are assay- and location-dependent, and that their combination is therefore helpful to singling out the PM redox-active compounds driving its oxidative properties.

Source: International Journal of Environmental Research and Public Health

DOI: 10.3390/ijerph19137778

Authors: Maria Chiara Pietrogrande, Giorgia Demaria, Cristina Colombi, Eleonora Cuccia, Umberto Dal Santo

Institutions: University of Ferrara, Azienda Regionale per la protezione dell'ambiente Lombardia

Language: English

Topic: Atmospheric chemistry and aerosols

Subfield: Atmospheric Science

Field: Earth and Planetary Sciences

Domain: Physical Sciences

SDGs: Good health and well-being, Sustainable cities and communities

Open Access status: gold

Estimated APC paid: $2,618