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KINETICS AND MECHANISM OF THE CURTIUS REARRANGEMENT OF m-NITROBENZOYL AZIDE IN AQUEOUS SOLUTIONS OF SULFURIC ACID

Year: 2022

Type: article

Abstract: The kinetics and mechanism of the Curtius rearrangement of m-nitrobenzoyl azide in aqueous solutions of sulfuric acid of various concentrations has been studied. An increase of the acidity of the reaction solution an increase in the acidity of the reaction solution leads to an acceleration of the rearrangement. The rate-limiting step of the reaction is the rearrangement of the protonated form of m-nitrobenzoyl azide to the corresponding isocyanate

Source: Bulletin of the Saint Petersburg State Institute of Technology (Technical University)

DOI: 10.36807/1998-9849-2022-61-87-51-56

Authors: Yuliya N. Pavlyukova, Natalija V. Kudryavtseva, Vladimir А. Ostrovskii

Language: English

Topic: Physical Organic Chemistry and Reaction Kinetics

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: diamond

OpenAlex ID: W4291313402

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