Work

Electrochemical Synthesis of Hetero[7]helicenes Containing Pyrrole and Furan Rings via an Oxidative Heterocoupling and Dehydrative Cyclization Sequence

Year: 2023

Type: article

Abstract: The electrochemical synthesis of hetero[7]helicenes including pyrrole and furan rings has been established. A single electrochemical operation led to an oxidative heterocoupling and dehydrative cyclization sequence to afford oxaza[7]helicenes in 50–86% yields with 45–77% Faradic efficiencies. Their derivatization and chiroptical properties were also investigated. magnified image

Source: Advanced Synthesis & Catalysis

DOI: 10.1002/adsc.202201262

Authors: Mohamed S. H. Salem, Md. Imrul Khalid, Makoto Sako, Keigo Higashida, Charlie Lacroix, Masaru Kondo, Ryo Takishima, Taisei Taniguchi, Masahiro Miura, Giang Vo‐Thanh, Hiroaki Sasai, Shinobu Takizawa

Institutions: Suez Canal University, The University of Osaka, Centre National de la Recherche Scientifique, Université Paris-Saclay, Institut de Chimie Moléculaire et des Matériaux d'Orsay, Ibaraki University, Institute for Open and Transdisciplinary Research Initiatives

Language: English

Topic: Synthesis and Properties of Aromatic Compounds

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: green

Funders: Hoansha Foundation, Ministry of Education, Culture, Sports, Science and Technology, Japan Society for the Promotion of Science

Awards: G3360520739, Development of environmentally friendly asymmetric carbon-carbon bond formations using highly active multifunctional base metal complexes, Synergy of biocatalysts and transition metal catalysts: Innovative syntheses of optically pure, highly functional organic compounds, Electrochemical Synthesis of Chiral Heterohelicenes

OpenAlex ID: W4315465002

FWCI: 2.335

Cites: 85

Cited by: 24

Related to: 10