Work

Allylsulfones through Palladium‐Catalyzed Allylic C−H Sulfonylation of Terminal Alkenes

Year: 2023

Type: article

Abstract: Two previously unknown protocols for Pd‐catalyzed allylic C−H sulfonylation of terminal alkenes have been developed. While the former consists of a direct Pd(II)‐catalyzed oxidative C−H allylic sulfonylation in the presence of sulfinate anions, the latter involves a sequential one‐pot Pd(II)‐catalyzed C−H allylic acetoxylation followed by a Pd(0)‐catalyzed sulfonylation. The scope of both protocols was studied on 25 examples.

Source: European Journal of Organic Chemistry

DOI: 10.1002/ejoc.202201493

Authors: Tingting Chen, Jassmin Lahbi, Gianluigi Broggini, Alexandre Pradal, Giovanni Poli

Institutions: Centre National de la Recherche Scientifique, Sorbonne Université, Institut Parisien de Chimie Moléculaire, University of Insubria

Language: English

Topic: Sulfur-Based Synthesis Techniques

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: hybrid

Estimated APC paid: $4,120

Funders: China Scholarship Council, Centre National de la Recherche Scientifique, Sorbonne Université