Work

A mononuclear cobalt( iii ) carboxylate complex with a fully O-based coordination sphere: Co III –O bond homolysis and controlled radical polymerisation from [Co(acac) 2 (O 2 CPh)]

Year: 2023

Type: article

Abstract: Complex [Co III (acac) 2 (O 2 CPh)], readily prepared from [Co II (acac) 2 ] and benzoyl peroxide, thermally generates benzoate radicals and initiates an organometallic-mediated radical polymerisation of vinyl acetate.

Source: Dalton Transactions

DOI: 10.1039/d3dt00910f

Authors: Maxime Michelas, Jean-Claude Daran, Alix Sournia-Saquet, Christophe Fliedel, Rinaldo Poli

Institutions: Centre National de la Recherche Scientifique, Université Toulouse III - Paul Sabatier, Institut National Polytechnique de Toulouse, Laboratoire de Chimie de Coordination, Université de Toulouse, Institut Universitaire de France

Language: English

Topic: Organometallic Complex Synthesis and Catalysis

Subfield: Organic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: green

Funders: Agence Nationale de la Recherche, Centre National de la Recherche Scientifique

Awards: Metal complexes for polymerization mechanism switching, G3010527862

OpenAlex ID: W4367358552

FWCI: 0.292

Cites: 70

Cited by: 3

Related to: 10