Work

Leveraging Halogen Interactions for a Supramolecular Nanotube

Year: 2023

Type: preprint

Abstract: Supramolcular nanotubes in a single crystal were produced from halogenated macrocycles by balancing hydrogen bonds and halogen interactions. A new iodinated macrocycle was prepared, crystallized, and a bonding analysis was performed to evaluate the nature and strength of the involved type I I…I interactions and C=O…I halogen bonds.

Source: ChemRxiv

DOI: 10.26434/chemrxiv-2023-dp6kw

Authors: Sergey Fisher, Lorraine Malaspina, Cristian Gozálves Martinez, Alessandro Prescimone, Yaser Balmohammadi, Simon Grabowski, Tomáš Šolomek

Institutions: University of Bern, University of Amsterdam, University of Basel

Language: English

Topic: Crystallography and molecular interactions

Subfield: Physical and Theoretical Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: green

Funders: National Science Foundation, University of Bern, Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung, European Research Council

Awards: Three-Dimensional Molecular Electron Acceptors for Efficient Electron-Transporting Materials, G8626770805, Toblerone-Shaped Polymers: Bridging the Gap between Conjugated Polymers and Carbon Nanotubes

OpenAlex ID: W4388550720

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