Work

CAAC-stabilised 9,10-diboraanthracene: an electronically and structurally flexible platform for small-molecule activation and metal complexation

Year: 2023

Type: article

Abstract: In its bent form a cyclic alkyl(amino)carbene (CAAC)-stabilised 9,10-diboraanthracene diradical enables concerted small molecule activation by the two boron centres, while in its planar form it acts as an η 6 -heteroarene ligand to group 6 carbonyls.

Source: Dalton Transactions

DOI: 10.1039/d3dt03787h

Authors: Maximilian Dietz, Merle Arrowsmith, Holger Braunschweig

Institution: University of Würzburg

Language: English

Topic: Synthesis and characterization of novel inorganic/organometallic compounds

Subfield: Inorganic Chemistry

Field: Chemistry

Domain: Physical Sciences

Open Access status: bronze

Funders: Deutsche Forschungsgemeinschaft, Studienstiftung des Deutschen Volkes

Awards: G6270003680, 500 MHz NMRSpektrometerkonsole