Work

Metal–carbon bonding in early lanthanide substituted cyclopentadienyl complexes probed by pulsed EPR spectroscopy

Year: 2024

Type: article

Abstract: We report relaxation and ligand hyperfine effects in an isostructural series of early lanthanide substituted cyclopentadienyl complexes, [Ln(Cp tt ) 3 ] (Ln = Ce, Nd, Sm; Cp tt = C 5 H 3 t Bu 2 -1,3), by pulsed EPR spectroscopy.

Source: Chemical Science

DOI: 10.1039/d3sc06175b

Authors: Lydia E. Nodaraki, Jingjing Liu, Ana-Maria Ariciu, Fabrizio Ortu, Meagan S. Oakley, Letitia Birnoschi, Gemma K. Gransbury, Philip J. Cobb, Jack Emerson-King, Nicholas F. Chilton, David P. Mills, Eric J. L. McInnes, Floriana Tuna

Institution: University of Manchester

Language: English

Topic: Lanthanide and Transition Metal Complexes

Subfield: Materials Chemistry

Field: Materials Science

Domain: Physical Sciences

Open Access status: diamond

Funders: Ministry of Defence, Royal Society, Marie Curie, University of Manchester, European Commission, China Scholarship Council, Natural Sciences and Engineering Research Council of Canada, Engineering and Physical Sciences Research Council, H2020 European Research Council, H2020 Marie Skłodowska-Curie Actions

Awards: Designing Highly Axial Lanthanide Single Molecule Magnets, G1425315200, G162407419, G1942994768, G2049477843, G4256235893, G4581035372, High Intensity High Sensitivity X-ray Diffaction, G7107606567, EPR NRF Core Equipment Bid, G7626776571, A National Research Facility for EPR Spectroscopy, 2022-2027

OpenAlex ID: W4390920192

FWCI: 1.168

Cites: 47

Cited by: 12

Related to: 10