Year: 2025
Type: article
Abstract: Two new cage-structured compounds—NbCu2Zn20 and HfCu2Zn20—belonging to the MM’2X20 (M, M’ = transition or rare earth metals, and X = Al, Zn, or Cd) family of structures have been synthesized via the self-flux method. The new compounds crystallize in the space group Fd3¯m with lattice parameter 13.9013(2) Å for NbCu2Zn20 and 13.9856(2) Å for HfCu2Zn20. The structures follow the expected metallic radii trend in MM’20Zn20 (M = Nb or Hf, M’ = Mn, Fe, Co, Ni, and Cu). While NbCu2Zn20 is stoichiometric, HfCu2Zn20 exhibits Cu/Zn site mixing and Hf-site underoccupancy, resulting in a final stoichiometry of Hf0.96Cu1.67Zn20.33 (Hf1–δCu2–xZn20+x, δ = 0.04, x = 0.33).
Source: Crystals
Authors: Sarah M. Longworth, Marium M. Mou, Nusrat Yasmin, Md Fahel Bin Noor, Ridwan Sakidja, Tiglet Besara
Institution: Missouri State University
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $2,534
OpenAlex ID: W4409702234