Work

Processing Strategies for High-Performance Polyester-Based Adhesives Reinforced by Bio-Derived Nanoparticles

Year: 2025

Type: article

Abstract: This study explores the enhancement of mechanical and adhesive properties of unsaturated polyester resins (UPR) through the incorporation of bio-derived chitin nanowhiskers (CNWs) into the polymer matrix. CNWs are high-performance nanoparticles extracted from chitin, an abundant and renewable biopolymer. The research investigates the effects of processing strategies and CNW loadings on the chemical structure, thermal behaviour, mechanical strength, and adhesive performance of UPR–CNW nanocomposites. CNWs were incorporated into the UPR matrix via slurry compounding using different suspension media, including ethanol, acetone, and methyl ethyl ketone, and through direct mechanical mixing with CNW dry powders. Experimental results show that the thermal and mechanical properties of the nanocomposites are highly sensitive to both the thermal history during processing and the choice of suspension medium. Most importantly, the optimal adhesive performance was achieved via slurry compounding with a CNW suspension in ethanol, following an evaporative pre-treatment of the suspension to reduce ethanol content and thereby minimize transesterification of the polyester matrix.

Source: Journal of Manufacturing and Materials Processing

DOI: 10.3390/jmmp9120382

Authors: Nathan R. Hsieh, Aaron Guan, Saraswati Koul, Siu N. Leung

Institution: York University

Language: English

Topic: Polymer Science and Applications

Subfield: Polymers and Plastics

Field: Materials Science

Domain: Physical Sciences

SDG: Responsible consumption and production

Open Access status: gold

Estimated APC paid: $2,172