Structural, Optical, and Conduction Relaxation Properties of TlCrP 2 O 7 Driven by Nonoverlapping Small Polaron Tunneling
Year: 2026
Type: article
Abstract: High Resolution Image Download MS PowerPoint Slide This work provides an in-depth examination of the structural, optical, electrical, and dielectric characteristics of TlCrP 2 O 7, prepared using a conventional solid-state reaction route. X-ray diffraction (XRD) analysis confirms the formation of a highly crystalline single phase with monoclinic symmetry ( P 2 1 / c ). Complementary Raman and infrared spectroscopy further validate the structural framework and reveal the characteristic internal and external vibrational modes associated with the pyrophosphate network. Optical characterization revealed a direct band gap of 2.99 eV and an Urbach energy of 0.48 eV, reflecting significant electronic transitions within the lattice. Impedance measurements indicated thermally activated conduction, with activation energies of 0.52 eV for grains and 0.47 eV for grain boundaries, successfully modeled using an equivalent circuit incorporating constant phase elements to capture microstructural effects. The AC conductivity obeys Jonscher’s universal power law, indicating that charge transport occurs through a nonoverlapping small polaron tunneling mechanism. Dielectric studies reveal pronounced non-Debye relaxation and significant space-charge polarization, both strongly influenced by temperature, frequency, and grain-boundary effects. Overall, these results emphasize the crucial influence of microstructure on charge transport and dielectric behavior, highlighting TlCrP 2 O 7 as a promising material for electronic and optoelectronic applications.
Source: ACS Omega
Institution: University of Sfax
Language: English
Subfield: Materials Chemistry
Field: Materials Science
Domain: Physical Sciences
Open Access status: gold
Estimated APC paid: $1,935
OpenAlex ID: W7124719084